A woman is chloroformed while smoking a cigarette and wakes up tied up in the woods.
Note: this comic was originally published in English but I can't find the English edition
Black Widow betrays Tony Stark, killing his butler Jarvis and holding him at gun point, however Tony is able to paralyze her using nanites that he injected into her bloodstream and than knocks her unconscious with a wine bottle.
Source: https://readcomiconline.to/Comic/Ultimates-2